水果葡萄,还有香蕉,罗望子,柑橘,也含有酒石酸,一种白色结晶有机酸,自然存在于许多其他水果中。 发酵过程自然产生酒石酸钾,这种盐给酒石奶油起了名字。 作为发酵粉出售时,经常与碳酸氢钠混合,在食品制作中用作发酵剂。 食物本身就是一种抗氧化剂(E334),赋予它们独特的酸味。 自然产生的酒石酸是合成有机化学品的宝贵起点。 酒石酸是琥珀酸的二羟基衍生物,是一种具有二质体和醛酸性质的α-羟基-羧酸。

本物质的组成:

一种在第二和第三碳原子上有两个OH基团和两个羧酸(COOH)基团的四碳有机酸,涉及第一和第四碳,酒石酸(HOOCH(OH)CH(OH)CH(OH)COOH;C4H6O6)。 酒石酸有三种不同的异构体。 两种形式的分子不能叠加在镜像上,因为它们是手性异构体。 L(+)酒石酸异构体是人工合成的酒石酸,经常在葡萄中天然发现,以供处理。 通常,这种形式被称为”右倾形式”。 酒石酸D(-)型在性质上较少见,但几乎没有实际应用。 中酒石酸,一种也可以产生的无手性异构体,是第三种形式。

该物质的特性:

酒石酸,一种有机酸,是无色的结晶固体,没有气味。 这种物质有助于许多水果的味道,并具有强烈的酸味。 它是微生物稳定的,具有高钾(酸-解离平衡常数;酸度强度的量度)。 它自然存在于葡萄、香蕉和罗望子等植物中。 几个世纪以来,酿酒人一直对酒石酸很敏感。 然而,瑞典化学家卡尔·威廉·舍尔在1769年发明了化学萃取工艺。
化学手性是在酒石酸的帮助下首次发现的。 1832年,Jean Baptiste Biot首次注意到酒石酸能够旋转偏振光。 1847年,路易斯·巴斯德通过研究酒石酸铵钠的晶体形式,继续进行这项研究,他发现它是手性的。 巴斯德通过手工筛选各种形状的晶体,制得第一个纯左旋酒石酸样品。
一些著名的酒石酸衍生物包括酒石奶油(酒石酸钾)、罗谢尔盐(酒石酸钾钠,一种温和的泻药)和酒石呕吐剂(酒石酸锑钾)。 在不对称合成中,酒石酸二异丙酯作为共催化剂使用,由于可以防止苹果酸的生成,因此,如果大量摄取,就会麻痹并杀死肌肉毒素是肌肉毒素。 对于一个人来说,5.3克/千克是中位致死剂量(LD),而4.4克/千克是小鼠的LD。 这意味着许多食物,特别是酸味的糖果,可能安全地含有它,因为要超过500克(18盎司)才能杀死体重70公斤(150磅)的人。 酒石酸是E334,用作食物添加剂的抗氧化剂;酒石酸盐是用作抗氧化剂或乳化剂的其他添加剂。 在水中加入奶油酒石会产生一种悬浮液,这种悬浮液对铜币的清洁效果非常好,因为酒石酸盐溶液可以溶解铜(II) 硬币表面的氧化物。 铜的络合物(II)和生成的酒石酸盐容易溶于水。

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